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Battery voltage reversal

Today I learned that a battery can experience a voltage reversal. I never heard of this before.

 

The background: there is some device in our fridge which starts to play a melody once the door is open for too long.

The device is operated using 3 Alkaline AA Ikea batteries (ALKALISK, 1.5V LR6 AA AM3 MN1500 - 23050).

All batteries  in series connected produce 0.8V ... so I though they are all almost empty.

 

I was more than surprised to measure that the first and the second battery have got 0.8V, and the third has got -0.8 V (yes, minus 0.8V) !

 

According to Wikipedia this may happen to re-chargable cells:

 

"when a battery made of several cells connected in series is deeply discharged. The problem occurs due to the different cells in a battery having slightly different capacities. When one cell reaches discharge level ahead of the rest, the remaining cells will force the current through the discharged cell.

 

Also, I can see some little bulge on the discharged battery - an indication of a chemical reaction.

 

I didn't find a hint this can happen to Alkaline batteries. Interesting.

 

 

The picture has been shared under CC BY-SA 3.0 license. Source.